Tremendous efforts have been dedicated to investigating alternative technologies. Dual-ion batteries (DIBs) represent an emerging battery technology with an attractive future such as high working voltage and a high-power density enabled by a “nonrocking chair” operation. Research in DIBs is still at an early stage.
As in any battery, the energy density of a DIB depends on the voltage and capacity, both parameters being determined by anion hosting materials. A graphite cathode can deliver a discharge capacity of around 100 mAh g −1 and a high working voltage beyond 4.5 V with LiPF 6 in EMC as an electrolyte.
In 2012, Placke et al. first introduced the definition “dual-ion batteries” for the type of batteries and the name is used till today. To note, earlier DIBs typically applied graphite as both electrodes, liquid organic solvents and lithium salts as electrolytes.
DIBs possess potentially attractive properties/performance and present some potentials as next-generation rechargeable batteries but there are still a lot of technical and scientific issues uncertain, which need more efforts to explore. All of the authors declare there is no interest conflict.
Fig. 9. Operational working principles of the dual graphite batteries within a diluted (left) and highly (right) concentrated LiTSFI electrolyte, in which the abbreviation SSIP corresponds to a solvent separated ion pair, CIP designates an ion pair in contact, and AGG denotes aggregated ions.
DIBs were initially known as dual-graphite batteries, where both anions and cations separately intercalate into graphite electrodes during the charge-discharge process. The anion intercalation into the host material enables DIBs in non-aqueous electrolyte to feature a high operating voltage, which also contributes to their enhanced energy density.
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