The lithium plating phenomenon, which is also called Li deposition, is a key phenomenon triggering TR when LIB is overcharged. For the analysis of the internal reaction of NCM battery, the heat generated from the dissolution of Mn and the deposition of Li gradually becomes the primary factor driving heating during the initial phase of overcharging.
Alleviating and restraining thermal runaway (TR) of lithium-ion batteries is a critical issue in developing new energy vehicles. The battery state of charge (SoC) influence on TR is significant. This paper performs comprehensive modeling and analysis with the non-uniform distribution of SoCs at the module level.
Severe swelling of the battery can usually be observed during overcharge process, due to the accumulation of gas from those side reactions , . The battery will rupture once the internal pressure exceeds its limit , resulting in deformation of battery structure and possible internal short circuit inside the battery , .
As seen, once the battery was discharged to 3.4 V, the voltage and current of the battery exhibited a phenomenon of sharp decline such that the discharging current was quite small when the battery voltage decreased below 0.5 V. After that, it was a long-time discharge where the current was near 0 A.
Where, the battery was discharged from 4.2 to 0.2 V at a CC of 1C. As seen, once the battery was discharged to 3.4 V, the voltage and current of the battery exhibited a phenomenon of sharp decline such that the discharging current was quite small when the battery voltage decreased below 0.5 V.
Further analysis on the onset temperature of thermal runaway helps to reveal the overcharge-induced thermal runaway mechanism of lithium-ion batteries. The result shows that rupture of the pouch and separator melting are the two key factors for the initiation of thermal runaway during overcharge process. 1. Introduction
Researchers Discover the Mechanism Responsible for "Self-Discharge…
To find the cause of self-discharge, scientists need to identify the complex chemical mechanisms that trigger the degradation process in the battery. Lithium-ion batteries are rechargeable and use lithium ions to store energy. The cathode and the electrolyte are two key components in lithium-ion batteries. The battery''s longevity can be influenced by the …
Thermal runaway propagation characteristics of lithium-ion batteries …
TR of a lithium-ion battery refers to the irreversible rapid temperature rise of batteries under various abuse conditions, such as overheating, overcharge, over-discharge [2, 3], needling [4, 5], and extrusion. The energy released by TR of a single battery and its damage to the battery system is limited. However, the TR propagation in a battery pack is a typical …
Advancements in the safety of Lithium-Ion Battery: The Trigger ...
As the components of an energy storage system with excellent performance, lithium-ion batteries (LIBs) have the advantage of low self-discharge rate, long cycle life, high specific energy and relatively small impact on the environment. Therefore, the LIBs are widely used in new energy EVs [1], [2], [3]. Revealed from the development process in the 80 s, …
Effects of over-discharging cycling on battery degradation at low ...
In this paper, the degradation characteristics were investigated by discharging to 2.75- 2 hours, respectively. The results show that capacity fades linearly except for the 0 V-2 h cell that fades at an accelerated rate. The fade rates increase with decreasing discharging voltage.
Fault mechanism study on Li-ion battery at over-discharge and …
A detailed research on fault mechanism of lithium (Li)-ion battery at over-discharge condition is reported in this study. Cells were cycled with different depths of discharge and reference performance tests were performed to extract parameters in dynamic and equilibrium conditions. The over-discharge process indicates that the abrupt change of ...
Thermal runaway propagation characteristics of lithium-ion …
Alleviating and restraining thermal runaway (TR) of lithium-ion batteries is a critical issue in developing new energy vehicles. The battery state of charge (SoC) influence …
Overcharge behaviors and failure mechanism of lithium-ion …
In this paper, the overcharge performance of a commercial pouch lithium-ion battery with Li y (NiCoMn) 1/3 O 2 -Li y Mn 2 O 4 composite cathode and graphite anode is …
Thermal runaway propagation characteristics of lithium-ion batteries …
Alleviating and restraining thermal runaway (TR) of lithium-ion batteries is a critical issue in developing new energy vehicles. The battery state of charge (SoC) influence on TR is significant. This paper performs comprehensive modeling and analysis with the non-uniform distribution of SoCs at the module level. First, a numerical ...
Understanding the Battery SOE (State of Energy) of …
Voltage Cutoff and Protection: Many lithium-ion batteries include built-in protection circuits that prevent over-discharge. When the battery reaches a critically low level, it may trigger a voltage cutoff to protect the …
Study on Discharge Characteristic Performance of New Energy …
In order to evaluate the safety performance of batteries in the laboratory testing of driving conditions of electric vehicles, this paper simulated and compared the discharge characteristics of ...
Evaluating fault detection strategies for lithium-ion batteries in ...
Although over-discharge is seldom the primary trigger for thermal runaway, cells that have been over-discharged suffer from permanent capacity loss and shifts in thermal stability. Several studies on over-discharge, spanning voltages from 0.0 to 2.0 V, were conducted. Overcharging at 0V exacerbated the situation, leading to unpredictable behavior . Research …
Impacts of Current Rates on the Degradation Behaviors of Lithium-Ion ...
It is found that battery capacity experiences obvious degradation during over-discharge cycling, while the current rate is shown to have little impact on the degraded capacity within a unit cycle. Therefore, nearly all the over-discharged batteries present a linear degradation rate as the over-discharge cycling proceeds, 0.05%/cycle.
Effects of over-discharging cycling on battery degradation at low ...
In this paper, the degradation characteristics were investigated by discharging to 2.75- 2 hours, respectively. The results show that capacity fades linearly except for the 0 V-2 h cell that fades …
Advancements in the safety of Lithium-Ion Battery: The Trigger ...
In this review paper, the factors triggering TR in LIBs, the consequences of TR and the current available methods for mitigating TR are summarized. More specifically in the first part, the major causes of LIB thermal runaway are examined from three primary triggering …
Recent advances of overcharge investigation of lithium-ion batteries ...
Key factors for battery overcharge safety, such as cathode materials, electrolyte safety, and charging current are concluded in this review. Compared to external protection devices (such as BMS, OSD, CID), the internal protection of …
Impacts of Current Rates on the Degradation Behaviors of Lithium …
It is found that battery capacity experiences obvious degradation during over-discharge cycling, while the current rate is shown to have little impact on the degraded …
Heat generation effect and failure mechanism of pouch-type …
Heat generation is a crucial factor for lithium-ion batteries during the charge and discharge process, which can trigger serious safety issue such as fire hazard and explosion. …
Fault mechanism study on Li-ion battery at over-discharge and its ...
A detailed research on fault mechanism of lithium (Li)-ion battery at over-discharge condition is reported in this study. Cells were cycled with different depths of …
Journal of Energy Storage
Heat generation is a crucial factor for lithium-ion batteries during the charge and discharge process, which can trigger serious safety issue such as fire hazard and explosion. Over-discharge is a common inducement which can result in not only heat generation effect, but electrode and electrolyte failure.
Effects of overdischarge on performance and thermal stability of a …
Alleviating and restraining thermal runaway (TR) of lithium-ion batteries is a critical issue in developing new energy vehicles. The battery state of charge (SoC) influence …
Recent advances of overcharge investigation of lithium-ion …
Key factors for battery overcharge safety, such as cathode materials, electrolyte safety, and charging current are concluded in this review. Compared to external …
Investigation of a commercial lithium-ion battery under overcharge/over …
However, one of the major problems is the safety issue, especially the failures of LIBs induced by extreme conditions such as external forces, high temperatures, low temperatures, overcharge and over-discharge. 1–5 An LIB may experience overcharge or over-discharge when it is used in a battery pack because of the capacity variation of different batteries in the pack and the …
Effects of overdischarge on performance and thermal stability of …
Alleviating and restraining thermal runaway (TR) of lithium-ion batteries is a critical issue in developing new energy vehicles. The battery state of charge (SoC) influence on TR is...
Heat generation effect and failure mechanism of pouch-type …
Heat generation is a crucial factor for lithium-ion batteries during the charge and discharge process, which can trigger serious safety issue such as fire hazard and explosion. Over-discharge is a common inducement which can result in not only heat generation effect, but electrode and electrolyte failure.
Overcharge behaviors and failure mechanism of lithium-ion batteries ...
In this paper, the overcharge performance of a commercial pouch lithium-ion battery with Li y (NiCoMn) 1/3 O 2 -Li y Mn 2 O 4 composite cathode and graphite anode is evaluated under various test conditions, considering the effects of charging current, restraining plate and heat dissipation.
Journal of Energy Storage
Heat generation is a crucial factor for lithium-ion batteries during the charge and discharge process, which can trigger serious safety issue such as fire hazard and explosion. …
Impacts of Current Rates on the Degradation Behaviors of Lithium-Ion ...
The over-discharge can significantly degrade a lithium-ion (Li-ion) batterys lifetime. Therefore, it is important to detect the over-discharge and prevent severe damage of the Li-ion battery.
Advancements in the safety of Lithium-Ion Battery: The Trigger ...
In this review paper, the factors triggering TR in LIBs, the consequences of TR and the current available methods for mitigating TR are summarized. More specifically in the first part, the major causes of LIB thermal runaway are examined from three primary triggering factors, including mechanical abuse, electrical abuse and thermal abuse.
Study on the parameter identification of lithium-ion battery …
With the impetus of the new energy market, Li-ion batteries 3–6 have undergone rapid development and has become the main energy storage method in fields, such as mobile devices, electric vehicles, and aerospace. 7,8 Using Li-ion batteries with high energy density and high discharge rate as the primary energy source of pulsed power systems can further …
A Review on the Fault and Defect Diagnosis of Lithium …
The battery system, as the core energy storage device of new energy vehicles, faces increasing safety issues and threats. An accurate and robust fault diagnosis technique is crucial to guarantee the safe, reliable, and …