The review focuses on recent studies on spinel lithium titanate (Li 4 Ti 5 O 12) for the energy storage devices, especially on the structure the reversibility of electrode redox, as well as the synthesis methods and strategies for improvement in the electrochemical performances. 1. Introduction
Lithium titanate, or lithium titanate oxide (LTO) batteries, are rechargeable batteries that use lithium titanate oxide as the anode material. These batteries fall under the lithium titanate classification. Their chemistry is based on the exchange of lithium ions between the cathode and the anode.
Porous lithium titanate nanosheets was developed via a simple hydrothermal method and used as an anode for SIBs by Liang and partners . The optimized sample showed reversible capacities of 123.2 mAh·g −1 and a capacity retention of about 90.7% after 1000 cycles at a current density of 0.5 A·g −1.
Lithium titanate batteries offer many advantages over other lithium-ion chemistries, including: Longer cycle life. Increased safety. Wider working temperature range. Faster charge/discharge rates. However, energy density is relatively low among these batteries. In addition, high C-rates inevitably impact the battery’s capacity over time.
Typically, a battery reaches its end of life when its capacity falls to 80% of its initial capacity. That said, lithium titanate batteries’ capacity loss rate is lower than for other lithium batteries. Therefore, it has a longer lifespan, ranging from 15 to 20 years.
Lithium titanate batteries are considered the safest among lithium batteries. Due to its high safety level, LTO technology is a promising anode material for large-scale systems, such as electric vehicle (EV) batteries.
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