Lithium metal batteries have garnered significant attention due to their high energy density and broad application prospects. However, the practical use of traditional liquid electrolytes is constrained by safety and stability challenges. In the exploration of novel electrolytes, solid-state electrolyte materials have emerged as a focal point.
An electrolyte with a broad potential range is beneficial for attaning interfacial stability and compatibility with higher working voltage and hence increasing the energy density of Li batteries .
Although solid polymer is one of the common organic electrolytes for the lithium battery, the problems of ionic conductivity and mechanical strength still need to be overcome for better performance. To overcome these problems, Zang et al. 135 developed a local high-concentration solid polymer electrolyte for the lithium battery.
The developments of all-solid-state lithium batteries (ASSLBs) have become promising candidates for next-generation energy storage devices. Compared to conventional lithium batteries, ASSLBs possess higher safety, energy density, and stability, which are determined by the nature of the solid electrolyte materials.
Inorganic filler/polymer composite solid electrolytes studied for use in various Li battery systems including Li-ion, Li-sulfur, and Li-metal batteries are evaluated. Promising designs of composite solid electrolytes and cathode materials used in all-solid-state Li batteries are also introduced.
Over the past 10 years, solid-state electrolytes (SSEs) have re-emerged as materials of notable scientific and commercial interest for electrical energy storage (EES) in batteries.
Solid-State Electrolyte for Lithium-Air Batteries: A Review
Traditional lithium–air batteries (LABs) have been seriously affected by cycle performance and safety issues due to many problems such as the volatility and leakage of liquid organic electrolyte, the generation of interface byproducts, and short circuits caused by the penetration of anode lithium dendrite, which has hindered its commercial application and …
Interface design for all-solid-state lithium batteries | Nature
The operation of high-energy all-solid-state lithium-metal batteries at low stack pressure is challenging owing to the Li dendrite growth at the Li anodes and the high interfacial resistance at ...
Solid-state polymer electrolytes in lithium batteries: …
Solid-state electrolytes (SSEs) have emerged as crucial components in the utilization of new-energy trams and everyday electronic devices due to their exceptional energy density, consistent power output, and …
Sulfide-based composite solid electrolyte films for all-solid-state ...
All-solid-state batteries with non-flammable solid electrolytes offer enhanced safety features, and show the potential for achieving higher energy density by using lithium …
Stable Binder Boosting Sulfide Solid Electrolyte Thin Membrane …
All-solid-state lithium metal batteries employing solid electrolyte and lithium anode are deemed to possess high safety and energy density, providing a new development strategy for electric vehicle and energy storage devices [1–7].Among all solid electrolytes, sulfide solid electrolytes with comparable ionic conductivity to liquid electrolytes are considered as the most …
Electrolyte Developments for All‐Solid‐State Lithium Batteries ...
The developments of all-solid-state lithium batteries (ASSLBs) have become promising candidates for next-generation energy storage devices. Compared to conventional lithium batteries, ASSLBs possess higher safety, energy density, and stability, which are determined by the nature of the solid electrolyte materials. In particular, various types ...
Composite solid electrolytes for all-solid-state lithium batteries
All-solid-state lithium sulfur batteries assembled using lithium metal, PEO 20 (LiCF 3 SO 3)Li 2 S-ZrO 2 composite solid electrolyte, and S-carbon composite cathode demonstrated moderate reversible capacity of 300 mA h g-1 at 70 °C.
Composite solid electrolytes for all-solid-state lithium batteries
All-solid-state lithium sulfur batteries assembled using lithium metal, PEO 20 (LiCF 3 SO 3)Li 2 S-ZrO 2 composite solid electrolyte, and S-carbon composite cathode …
Designing solid-state electrolytes for safe, energy-dense batteries ...
Solid-state batteries based on electrolytes with low or zero vapour pressure provide a promising path towards safe, energy-dense storage of electrical energy. In this …
Review on solid electrolytes for all-solid-state lithium-ion batteries ...
All-solid-state (ASS) lithium-ion battery has attracted great attention due to its high safety and increased energy density. One of key components in the ASS battery (ASSB) …
Superionic conducting vacancy-rich β-Li3N electrolyte for stable ...
All-solid-state lithium metal batteries using the vacancy-rich β-Li3N as SSE interlayers and lithium cobalt oxide (LCO) and Ni-rich LiNi0.83Co0.11Mn0.06O2 (NCM83) cathodes exhibit excellent ...
Designing lithium halide solid electrolytes
All-solid-state lithium batteries have attracted widespread attention for next-generation energy storage, potentially providing enhanced safety and cycling stability. The performance of such ...
Hybrid electrolytes for solid-state lithium batteries: Challenges ...
Hybrid electrolytes, which rationally integrate the benefits of single inorganic solid electrolytes (ISEs) and solid polymer electrolytes (SPEs) as well as achieve sufficiently high ionic conductivity, low interfacial impedance, and high electrode stability, have attracted significant interest for use in SSLBs.
Elastomeric electrolytes for high-energy solid-state lithium …
An elastomeric solid-state electrolyte shows desirable mechanical properties and high electrochemical stability, and is used to demonstrate a high-energy solid-state lithium...
The research progress on COF solid-state electrolytes …
In the exploration of novel electrolytes, solid-state electrolyte materials have emerged as a focal point. Covalent organic frameworks (COFs), with their large conjugated structures and unique electronic properties, are …
Elastomeric electrolytes for high-energy solid-state lithium batteries ...
An elastomeric solid-state electrolyte shows desirable mechanical properties and high electrochemical stability, and is used to demonstrate a high-energy solid-state lithium...
The research progress on COF solid-state electrolytes for lithium batteries
In the exploration of novel electrolytes, solid-state electrolyte materials have emerged as a focal point. Covalent organic frameworks (COFs), with their large conjugated structures and unique electronic properties, are gradually gaining attention as an emerging class of solid-state electrolyte materials.
Recent Progress of Polymer Electrolytes for Solid-State Lithium Batteries
In this review, the SPEs with different electrochemical windows are summarized and categorized, including (i) anode stable SPEs with good lithium metal compatibilities, (ii) cathode stable SPEs with good oxidation resistances, (iii) multilayer SPEs simultaneously withstanding reduction of a lithium anode and oxidation at high voltage.
Solid-state polymer electrolytes in lithium batteries: latest …
Solid-state electrolytes (SSEs) have emerged as crucial components in the utilization of new-energy trams and everyday electronic devices due to their exceptional energy density, consistent power output, and extended lifespan. Compared to nickel metal hydride batteries, they find superior application prospects within the electric vehicle domain.
Recent Progress of Polymer Electrolytes for Solid-State …
In this review, the SPEs with different electrochemical windows are summarized and categorized, including (i) anode stable SPEs with good lithium metal compatibilities, (ii) cathode stable SPEs with good oxidation …
Recent progress and fundamentals of solid-state electrolytes for …
To advance all-solid-state lithium rechargeable batteries, it is essential to study solid electrolyte materials with high lithium ion conductivity, low electronic conductivity, efficient charge transfer at the electrode interface, and stable electrochemical window when exposed to potential electrodes and lithium metal [3, 4].
The challenges and perspectives of developing solid-state
From the perspective of future development trend, energy issues will always accompany with the human development process. The development of new batteries that are friendly to the environment has become a global trend. Safe solid-state electrolytes with high ionic conductivity, excellent electrochemical property, high mechanical/thermal stabilfity, and good …
Formatted PVDF in lamellar composite solid electrolyte for solid-state ...
Solid polymer electrolytes (SPEs) hold great application potential for solid-state lithium metal battery because of the excellent interfacial contact and processibility, but being hampered by the poor room-temperature conductivity (∼ 10− 7 S·cm −1) and low lithium-ion transference number (({t_{{rm{L}}{{rm{i}}^ + }}})).Here, a lamellar composite solid electrolyte …
Phonon Engineering in Solid Polymer Electrolyte toward High …
Extensively-used rechargeable lithium-ion batteries (LIBs) face challenges in achieving high safety and long cycle life. To address such challenges, ultrathin solid polymer electrolyte (SPE) is fabricated with reduced phonon scattering by depositing the composites of ionic-liquid (1-ethyl-3-methylimidazolium dicyamide, EMIM:DCA), polyurethane (PU) and …
Composite solid electrolytes for all-solid-state lithium batteries
Compared to currently used liquid-electrolyte lithium batteries, all-solid-state lithium batteries are safer and possess longer cycle life and have less requirements on packaging and state-of-charge monitoring circuits. Among various types of solid electrolytes, composite solid electrolytes, which are composed of active or passive inorganic fillers and polymer matrices, …
Review on solid electrolytes for all-solid-state lithium-ion batteries ...
All-solid-state (ASS) lithium-ion battery has attracted great attention due to its high safety and increased energy density. One of key components in the ASS battery (ASSB) is solid electrolyte that determines performance of the ASSB.
Designing solid-state electrolytes for safe, energy-dense batteries ...
Solid-state batteries based on electrolytes with low or zero vapour pressure provide a promising path towards safe, energy-dense storage of electrical energy. In this Review, we consider...
Electrolyte Developments for All‐Solid‐State Lithium …
The developments of all-solid-state lithium batteries (ASSLBs) have become promising candidates for next-generation energy storage devices. Compared to conventional lithium batteries, ASSLBs possess higher safety, …
Sulfide-based composite solid electrolyte films for all-solid-state ...
All-solid-state batteries with non-flammable solid electrolytes offer enhanced safety features, and show the potential for achieving higher energy density by using lithium metal as the...